According to R. Yisroel Belsky, no. Employees are given a little leeway in giving customers extra or charging them less, in order to encourage the customer's use of the facilities. Specifically in regard to libraries, R. Belsky writes:
It could be that the librarian may feel that you're such an excellent customer that he'll waive the fee... Still, if you feel that the person is causing a loss to the library, you should pay the fine and not accept the favor.The same applies to waiters who give you a few extra french fries or charge you a little less in order to create a pleasant atmosphere. Big favor, however, might be theft.
Favors are not something that's outside of proper behavior in a business context. When limited to areas that create good will, the small amounts of favors that are done are not only proper and acceptable, but they're chiyuvim (requirements) as well.